Chemistry Solutions 2 Marks
Appeared in: 2025 (3 sets)
(a) Define Fuel cell. Write two advantages of fuel cell over ordinary cell. OR (b) Predict the products of electrolysis in each of the following : (i) A dilute solution of $\text{H}_2\text{SO}_4$ with platinum electrodes (ii) An aqueous solution of $\text{CuCl}_2$ with platinum electrodes
✓ Verified CBSE Marking Scheme Official Evaluation Steps & EL10 Insight

Solution for (a) Fuel Cell

Step 1 (Definition): [1 Mark]

A Fuel cell is a galvanic cell that converts the chemical energy of combustion of fuels (like $\text{H}_2$, $\text{CH}_4$, $\text{CH}_3\text{OH}$) directly into electrical energy.

Step 2 (Advantages): [1 Mark]

  • High Efficiency: Fuel cells are much more efficient than conventional methods (like burning fuels to produce heat, then steam, then electricity) as they are not limited by Carnot cycle efficiency.
  • Pollution-free: Since the byproduct is usually water ($\text{H}_2\text{O}$), they are eco-friendly and do not cause environmental pollution.

Solution for (b) Electrolysis Products

Step 1 (Governing Principles): [0.5 Mark]

The products of electrolysis depend on the standard electrode potentials of the ions present and the nature of the electrodes. For dilute $\text{H}_2\text{SO}_4$, water undergoes oxidation and reduction. For aqueous $\text{CuCl}_2$, $\text{Cu}^{2+}$ ions are preferentially discharged over $\text{H}^+$ ions at the cathode.

Step 2 (Step-by-Step Analysis): [1 Mark]

(i) Dilute $\text{H}_2\text{SO}_4$ with Pt electrodes:

  • At Cathode: $2\text{H}^+(aq) + 2e^- \rightarrow \text{H}_2(g)$
  • At Anode: $2\text{H}_2\text{O}(l) \rightarrow \text{O}_2(g) + 4\text{H}^+(aq) + 4e^-$

(ii) Aqueous $\text{CuCl}_2$ with Pt electrodes:

  • At Cathode: $\text{Cu}^{2+}(aq) + 2e^- \rightarrow \text{Cu}(s)$
  • At Anode: $2\text{Cl}^-(aq) \rightarrow \text{Cl}_2(g) + 2e^-$

Step 3 (Final Concluded Answer): [0.5 Mark]

  • (i) Products: $\text{H}_2$ gas at cathode and $\text{O}_2$ gas at anode.
  • (ii) Products: $\text{Cu}$ metal at cathode and $\text{Cl}_2$ gas at anode.

💡 EL10 Concept Insight: Think of a fuel cell like a battery that never runs out as long as you keep feeding it fuel, and electrolysis like a "tug-of-war" where the strongest ions win the right to turn into gas or metal at the electrodes!